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    A pseudo-nanophase-separation strategy enabled by supramolecular interactions is proposed to construct a ion-selective transport highway in polymeric membranes. “Side chains” are “grafted” onto polymer backbones via supramolecular interactions instead of covalent bonds. This simplifies membrane preparation and simultaneously protects backbones from chemical degradation caused by molecular…

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    • From the latest issue of @Chem "Supramolecular interactions enable pseudo-nanophase separation for constructing an ion-transport highway" @UT_YuGroup @HeqingTsingsen Sangshan Peng & others #S23MRS https://t.co/t0elRouHKI

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    Proton-electron dual conductors with a well-defined structure allow for efficient charge transport while promoting a fundamental understanding of dual conduction. Herein, we present Zn-HHTP-H2O, a proton-electron dual-conducting MOF, which serves as a functionalizable platform. We found that substituting H2O with urea leaves electrical conductivity nearly the same while increasing proton…

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    • Check out Jihye Park (@JPdaCheerleader) & colleagues' work on 2D conjugated metal-organic framework as a proton-electron dual conductor - read the full article in @Chem_CP #ACSSpring2023 https://t.co/y9CwNFfqHF

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    The O–H bond dissociation free energies (BDFEs) and their distribution are reported for nickel oxide electrode surfaces. These BDFEs and the H-atom binding isotherms are remarkably independent of any changes in the solvent in contact. The unprecedented medium independence establishes these as important intrinsic parameters to describe metal oxide redox reactivity.

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    • Medium-independent hydrogen atom binding isotherms of nickel oxide electrodes - read the full article by @hyunhonoh1123 @MayerPCET @yalechem @Chem_CP #ACSSpring2023 https://t.co/UaYZzmuGNz

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    The freezing of aqueous electrolytes and the catalytic performance deterioration in electrocatalysts hinder the ultralow-temperature operation of zinc air batteries (ZABs). This work finds that the 8 M KOH electrolyte exhibits a freezing point down to −120°C and develops an ultralow-temperature-tolerant FeCo-PC bifunctional electrocatalyst. This results in a ZAB with unprecedented battery…

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    • "Aqueous rechargeable zinc air batteries operated at -110 °C" @CityUHongKong Jun Fan, Chunyi Zhi Read more in @Chem_CP: https://t.co/npl2u2wssy

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    The freezing of aqueous electrolytes and the catalytic performance deterioration in electrocatalysts hinder the ultralow-temperature operation of zinc air batteries (ZABs). This work finds that the 8 M KOH electrolyte exhibits a freezing point down to −120°C and develops an ultralow-temperature-tolerant FeCo-PC bifunctional electrocatalyst. This results in a ZAB with unprecedented battery…

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    • "Aqueous rechargeable zinc air batteries operated at -110 °C" @CityUHongKong Jun Fan, Chunyi Zhi Read more in @Chem_CP: https://t.co/npl2u2wssy

  • Mashup Score: 2

    Natural enzymes capable of plastic degradation lack biostability in open environments. Jiang and colleagues chemically synthesized a non-biodegradable plastic-degrading enzyme that is composed of D-amino acids and is capable of degrading a variety of achiral plastics such as polyethylene terephthalate (PET). This work demonstrates a potential approach for gradating plastics in environments that…

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    • "Biodegrading plastics with a synthetic non-biodegradable enzyme" #ChinaAgriculturalUniversity Cong Guo, Li-Qun Zhang, Wenjun Jiang Read more in @Chem_CP: https://t.co/Mt8XHgr1dy